There is a specific heartbreak reserved for the moment you slice a beautiful loaf, only to find the knife coated in a sticky, shiny residue. The crumb looks wet. When you press it, it balls up like putty rather than springing back. It eats like raw dough.

There is a point of no return. A moment when a neglected starter stops being a culture of beneficial microbes and becomes a Petri dish for pathogens. This transition is chemical. It is driven by a single variable: pH.

The true clock of sourdough is not measured in minutes, but in pH. The transformation of dough from a simple mixture of flour and water into a complex, digestible, and flavorful loaf is driven by acidification. Understanding the curve of this drop is the difference between a loaf that is bland and gummy, and one that sings.